Goos-H\"{a}nchen-Like Shifts in Atom Optics

We consider the propagation of a matter wavepacket of two-level atoms through a square potential created by a super-Gaussian laser beam. We explore the matter wave analog of Goos-H\"{a}nchen shift within the framework of atom optics where the roles of atom and light is exchanged with respect to conventional optics. Using a vector theory, where atoms are treated as particles possessing two internal spin components, we show that not only large negative but also large positive Goos-H\"{a}nchen shifts can occur in the reflected atomic beam.Comment: 7 pages, 4 figure

Chlorine and Bromine Isotope Fractionation of Halogenated Organic Pollutants on Gas Chromatography Columns

Compound-specific chlorine/bromine isotope analysis (CSIA-Cl/Br) has become a useful approach for degradation pathway investigation and source appointment of halogenated organic pollutants (HOPs). CSIA-Cl/Br is usually conducted by gas chromatography-mass spectrometry (GC-MS), which could be negatively impacted by chlorine and bromine isotope fractionation of HOPs on GC columns. In this study, 31 organochlorines and 4 organobromines were systematically investigated in terms of Cl/Br isotope fractionation on GC columns using GC-double focus magnetic-sector high resolution MS (GC-DFS-HRMS). On-column chlorine/bromine isotope fractionation behaviors of the HOPs were explored, presenting various isotope fractionation modes and extents. Twenty-nine HOPs exhibited inverse isotope fractionation, and only polychlorinated biphenyl-138 (PCB-138) and PCB-153 presented normal isotope fractionation. And no observable isotope fractionation was found for the rest four HOPs, i.e., PCB-101, 1,2,3,7,8-pentachlorodibenzofuran, PCB-180 and 2,3,7,8-tetrachlorodibenzofuran. The isotope fractionation extents of different HOPs varied from below the observable threshold (0.50%) to 7.31% (PCB-18). The mechanisms of the on-column chlorine/bromine isotope fractionation were tentatively interpreted with the Craig-Gordon model and a modified two-film model. Inverse isotope effects and normal isotope effects might contribute to the total isotope effects together and thus determine the isotope fractionation directions and extents. Proposals derived from the main results of this study for CSIA-Cl/Br research were provided for improving the precision and accuracy of CSIA-Cl/Br results. The findings of this study will shed light on the development of CSIA-Cl/Br methods using GC-MS techniques, and help to implement the research using CSIA-Cl/Br to investigate the environmental behaviors and pollution sources of HOPs.Comment: 30 pages, 5 figure

Development of a hot water tank simulation program with improved prediction of thermal stratification in the tank

AbstractA simulation programSpiralSolwas developed in previous investigations to calculate thermal performance of a solar domestic hot water (SDHW) system with a hot water tank with a built-in heat exchanger spiral[1]. The simulation program is improved in the paper in term of prediction of thermal stratification in the tank. The transient fluid flow and heat transfer in the hot water tank during cooling caused by standby heat loss are investigated by validated computational fluid dynamics (CFD) calculations. Detailed CFD investigations are carried out to determine the influence of thickness and material property of the tank wall on thermal stratification in the tank. It is elucidated how thermal stratification in the tank is influenced by the natural convection and how the heat loss from the tank sides will be distributed at different levels of the tank at different thermal conditions. The existing equation of the heat loss removal factor used in SpiralSol is evaluated by means of the detailed CFD calculations. A generalized new equation for the heat loss removal factor is obtained by regression. The new equation calculates the heat loss removal factor for a given temperature gradient in the tank,taking into account the influences of tank volume, height to diameter ratio, tank insulation, thickness and material property of the tankand initial thermal conditions of the tank. The equation is validated for a tank volume between 150 l and 500 l, a tank height to tank diameter ratio of 1-5,a tank wall thickness of 1.5mm to 3mm for a stainless steel tank and a tank wall thickness of between 3mm to 5mm for a normal steel tank. Accuracy and reliability of the SpiralSol program with the improved prediction of heat loss removal factor will be examined in future investigations